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Acta Crystallographica Section E

Structure Reports Online

Volume 64, Part 10 (October 2008)


metal-organic compounds



Acta Cryst. (2008). E64, m1332-m1333    [ doi:10.1107/S1600536808030602 ]

Bis[[mu]-3-(1H-pyrazol-1-yl)benzonitrile-[kappa]2N:N']bis[perchloratosilver(I)]

C.-Y. Niu, H.-Y. Zhang, C.-L. Feng, X.-S. Wan and C.-H. Kou

Abstract: In the title centrosymmetric complex, [Ag2(ClO4)2(C10H7N3)2], the unique AgI ion is coordinated by an N atom from a carbonitrile group, an N atom from a symmetry-related pyrazole group and an O atom of a perchlorate ligand to form a distorted T-shaped environment. Two 3-(1H-pyrazol-1-yl)benzonitrile ligands each bridge two AgI ions to form a dinuclear complex. In the crystal structure, there are weak Ag...O interactions within the range 2.70-3.01 Å linking dimeric units into layers approximately parallel to (100). The O atoms of the perchlorate ligand are disordered over two sites with occupancies of 0.570 (11) and 0.430 (11), respectively.

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