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(Acetato-O)bis(1,10-phenanthroline-2N,N')copper(II) acetate heptahydrate

Acta Crystallographica Section E

Structure Reports Online

Volume 67, Part 4 (April 2011)

metal-organic compounds


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Acta Cryst. (2011). E67, m464    [ doi:10.1107/S1600536811009676 ]

(Acetato-[kappa]O)bis(1,10-phenanthroline-[kappa]2N,N')copper(II) acetate heptahydrate

B. Jing, L. Li, J. Dong and T. Xu

Abstract: In the title complex, [Cu(CH3CO2)(C12H8N2)2](CH3CO2)·7H2O, the central CuII ion is five coordinate, being bound to four N atoms from two 1,10-phenanthroline ligands and one O atom from an acetate anion in a strongly distorted square-pyramidal configuration. Hydrogen-bonded water molecules and an uncoordinated acetate anion form a two-dimensional polymeric structure parallel to (010). The cations are linked to this layer via O-H...O hydrogen bonds between one of the water molecules and the coordinated acetate anion.

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