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Acta Crystallographica Section E

Structure Reports Online

Volume 65, Part 1 (January 2009)

organic compounds

Acta Cryst. (2009). E65, o118-o119    [ doi:10.1107/S1600536808041950 ]


H.-K. Fun, R. Kia, A. C. Maity, S. Maity and S. Goswami

Abstract: The asymmetric unit of the title compound, C13H11IN2O, comprises two crystallographically independent molecules. The dihedral angles between the ring planes are 53.56 (9) and 72.14 (19)° in the two molecules. Pairs of intermolecular N-H...N hydrogen bonds and I...O interactions link neighbouring molecules into two different pairs of dimers, those involving N-H...N interactions having R22(8) ring motifs. Short intermolecular I...O [3.1458 (15) Å] and I...N [3.4834 (16) Å] contacts are present. The crystal structure is further stabilized by intermolecular C-H...[pi] interactions [3.565 (2) and 3.629 (2) Å].

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