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1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridomanganate(II)

Acta Crystallographica Section E

Structure Reports Online

Volume 66, Part 11 (November 2010)

metal-organic compounds

im2229 scheme

Acta Cryst. (2010). E66, m1414 [ doi:10.1107/S160053681004047X ]

1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridomanganate(II)

M. Guo and M. M. Zhao

Abstract: In the crystal structure of the title compound, (C₈H₁₅N₃)[MnCl₄], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetrahedral geometry. Each [MnCl₄]^2- anion is connected to the 1-cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane dications by N-HCl hydrogen bonds, forming chains parallel to [001].