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1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridomanganate(II)

Acta Crystallographica Section E

Structure Reports Online

Volume 66, Part 11 (November 2010)


metal-organic compounds



im2229 scheme

Acta Cryst. (2010). E66, m1414    [ doi:10.1107/S160053681004047X ]

1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridomanganate(II)

M. Guo and M. M. Zhao

Abstract: In the crystal structure of the title compound, (C8H15N3)[MnCl4], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetrahedral geometry. Each [MnCl4]2- anion is connected to the 1-cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane dications by N-H...Cl hydrogen bonds, forming chains parallel to [001].

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