It is the cache of ${baseHref}. It is a snapshot of the page. The current page could have changed in the meantime.
Tip: To quickly find your search term on this page, press Ctrl+F or ⌘-F (Mac) and use the find bar.

Bis[-2-(pyridin-2-yl)ethanolato]bis[bromidocopper(II)]

Acta Crystallographica Section E

Structure Reports Online

Volume 67, Part 11 (November 2011)


metal-organic compounds



fi2115 scheme

Acta Cryst. (2011). E67, m1612    [ doi:10.1107/S1600536811043637 ]

Bis[[mu]-2-(pyridin-2-yl)ethanolato]bis[bromidocopper(II)]

M. M. Shaikh, S. Mathur and M. J. Uddin

Abstract: The title compound, [Cu2Br2(C7H8NO)2], was synthesized by reaction of CuBr2 with 2-(pyridin-2-yl)ethanol (hep-H) in methanol. The asymmetric unit consists of one hep ligand and a CuBr unit. The Cu2+ ion is thereby coordinated by the N atom and the deprotonated hydroxy O atom in a distorted square-planar geometry that is completed by another O atom. The latter acts as bridging ligand towards the second, symmetry-equivalent, Cu atom, thus generating a centrosymmetric dimeric unit, with the inversion centre halfway between the Cu atoms. These units are linked via C-H...Br and C-H...O hydrogen bonds, leading to the formation of a hydrogen-bonded one-dimensional-polymeric chain along a..

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster