Acta Cryst. (2010). E66, m1156-m1157 [ doi:10.1107/S1600536810033246 ]
Abstract: The title one-dimensional coordination network, {[Eu2(NO3)6(C10H8N2O2)3]·2CH2Cl2}n, is isostructural with the previously reported Tb and Tl coordination networks and to its Gd analog. The EuIII cation is coordinated in a distorted tricapped trigonal-prismatic fashion by nine O atoms from three bridging 4,4'-bipyridine N,N'-dioxide ligands and three chelating nitrate anions. None of the atoms lie on a special position, but there is an inversion center located between the rings of one of the ligands. The network topology is ladder-like, and each ladder interacts with six neighboring ladders through C-HO hydrogen bonds. The packing motif of the ladders allows for the formation of channels that run parallel to the a axis; these channels are filled with CH2Cl2 solvent molecules that interact with the ladders through C-HO hydrogen bonds.
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