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cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-2O,O')iridium(III)

Acta Crystallographica Section E

Structure Reports Online

Volume 65, Part 4 (April 2009)


metal-organic compounds



Acta Cryst. (2009). E65, m440    [ doi:10.1107/S1600536809010204 ]

cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-[kappa]2O,O')iridium(III)

G.-Y. Xiao, P. Lei, H.-J. Chi, Z.-Z. Hu and X. Li

Abstract: In the title compound, [Ir(C15H9FNS)2(C5H7O2)], the Ir atom is hexacoordinated by three chelating ligands, with two cyclometalated 2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl ligands showing N,C-bidentate coordination and an O,O'-bidenate pentane-2,4-dionate anion, thereby forming a distorted octahedral enviroment.

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