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Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 8 (August 2012)


metal-organic compounds



br2207 scheme

Acta Cryst. (2012). E68, m1041    [ doi:10.1107/S1600536812030486 ]

Diiodido{2-[(4-methoxyphenyl)iminomethyl]pyridine-[kappa]2N,N'}zinc

S. Salehzadeh, M. Khalaj and S. Dehghanpour

Abstract: In the title complex, [ZnI2(C13H12N2O)], the ZnII atom has a distorted tetrahedral coordination. The organic ligand is bidentate, coordinating the ZnII atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal, weak C-H...I and C-H...O hydrogen bonds are observed, in addition to [pi]-[pi] stacking interactions, with a centroid-centroid distance of 3.72 (5) Å.

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