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Crystal and molecular structure of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex
Abstract
We report the synthesis of bis(4-bromo-N-(diethylcarbamothioyl)benzamido)nickel(II) complex of an benzoylthiourea derivative formulated as C24H28Br2NiN4O2S2. The structure of compound has been determined by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group, P21/c with unit cell dimensions of a = 12.9099(17) Å, b = 15.264(2) Å, c = 14.0287(19) Å, β = 92.140(4)o and V = 2762.5(6) Å3. In this compound, the nickel atom is coordinated by two sulphur and two oxygen atoms from two 4-bromo-N-(diethylcarbamothioyl)benzamide molecules forming an distorted square-planar geometry.
Keyword(s)
European Journal of Chemistry, 3 (1), (2012), 37-39
DOI: http://dx.doi.org/10.5155/eurjchem.3.1.37-39.591
Cited-By
[1]. Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes
Gün Binzet, Gülten Kavak, Nevzat Külcü, Süheyla Özbey, Ulrich Flörke, Hakan Arslan
Journal of Chemistry Volume: 2013 First page: 1 Year: 2013 
[2]. Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex
Gun Binzet, Ulrich Flörke, Nevzat Külcü, Hakan Arslan
European Journal of Chemistry Volume: 3 Issue: 2 First page: 211 Year: 2012
[3]. A review on the chemistry, coordination, structure and biological properties of 1-(acyl/aroyl)-3-(substituted) thioureas
Aamer Saeed, Ulrich Flörke, Mauricio F. Erben
Journal of Sulfur Chemistry First page: 1 Year: 2013
[4]. Monomeric/dimeric complexes of fac-[Re(CO)3]+ with benzoylthiourea derivatives
B. Schmitt, T.I.A. Gerber, E. Hosten, R. Betz
Inorganic Chemistry Communications Volume: 24 First page: 136 Year: 2012
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