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1-Bromomethyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide

Acta Crystallographica Section E

Structure Reports Online

Volume 66, Part 2 (February 2010)

organic compounds

Acta Cryst. (2010). E66, o377 [ doi:10.1107/S1600536810000292 ]

1-Bromomethyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide

A. D. Finke, D. L. Gray and J. S. Moore

Abstract: The title compound, C₇H₁₄BrN₂⁺·Br^-, was prepared by nucleophilic substitution of DABCO (systematic name: 1,4-diazabicyclo[2.2.2]octane) with dibromomethane in acetone. The structure features BrH close contacts (2.79 and 2.90 Å) as well as a weak bromine-bromide interaction [3.6625 (6) Å].