Acta Cryst. (2011). E67, m1872-m1873 [ doi:10.1107/S1600536811049567 ]
Abstract: In the title compound, (C12H24N)[Sn(CH3)3(C6H6O3P)2], the SnMe3 residues are axially coordinated by two monodentate [PhPO3H]- anions, leading to a trigonal-bipyramidal geometry for the SnIV atom. The two [SnMe3(PhPO3H)2]- anions in the unit cell are associated into infinite chains along the a axis by O-HO hydrogen bonds involving the hydroxy group of the hydrogen phenylphosphonate ion. The chains interact with one another via O-HO hydrogen bonds along the c axis. These networks of anions assemble with the dicyclohexylammonium ion through N-HO hydrogen bonds, forming a three-dimensional network.
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