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Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV)

Acta Crystallographica Section E

Structure Reports Online

Volume 67, Part 12 (December 2011)


metal-organic compounds



vn2021 scheme

Acta Cryst. (2011). E67, m1872-m1873    [ doi:10.1107/S1600536811049567 ]

Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV)

T. Diop, L. Diop, C. A. K. Diop, K. C. Molloy and G. Kociok-Köhn

Abstract: In the title compound, (C12H24N)[Sn(CH3)3(C6H6O3P)2], the SnMe3 residues are axially coordinated by two monodentate [PhPO3H]- anions, leading to a trigonal-bipyramidal geometry for the SnIV atom. The two [SnMe3(PhPO3H)2]- anions in the unit cell are associated into infinite chains along the a axis by O-H...O hydrogen bonds involving the hydroxy group of the hydrogen phenylphosphonate ion. The chains interact with one another via O-H...O hydrogen bonds along the c axis. These networks of anions assemble with the dicyclohexylammonium ion through N-H...O hydrogen bonds, forming a three-dimensional network.

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