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Hexakis(2-aminopyridinium) di-6-oxido-tetra-3-oxido-tetradeca-2-oxido-octaoxidodecavanadium(V) dihydrate

Acta Crystallographica Section E

Structure Reports Online

Volume 65, Part 3 (March 2009)


metal-organic compounds



Acta Cryst. (2009). E65, m267-m268    [ doi:10.1107/S1600536809004334 ]

Hexakis(2-aminopyridinium) di-[mu]6-oxido-tetra-[mu]3-oxido-tetradeca-[mu]2-oxido-octaoxidodecavanadium(V) dihydrate

C. Yuan, L. Lu, M. Zhu, Q. Ma and Y. Wu

Abstract: In the title compound, (C5H7N2)6[V10O28]·2H2O, the [V10O28]6- anion is generated by crystallographic inversion symmetry and each of the five vanadium centres adopts a distorted VO6 octahedral geometry. In the crystal structure, a network of N-H...O, N-H...(O,O) and O-H...O hydrogen bonds helps to establish the packing.

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