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Open Journal Systems Universidad Nacional de Colombia

Open Journal Systems

Solar photo-Fenton optimisation in treating carbofuran-contaminated water

Manuel Alejandro Hernández-Shek, Ana Cecilia Agudelo Henao, Claudia Mendoza Marín, Harlen Torres Castañeda

Abstract


Box-Benkhen design response-surface methodology was developed to optimise photo-Fenton degradation of carbofuran (C 12H 15NO 3) by using a compound parabolic collector pilot plant. The four variables considered in Box-Benkhen design model included carbofuran degradation percentage, initial carbofuran concentration, hydrogen peroxide [H 2O 2] concentration and iron [Fe 2+] concentration. Degradation was monitored by using total organic carbon concentration and high-performance liquid chromatography. A 93.2 mg l -1 carbofuran concentration was completely degraded in t 30W = 15 min with 17.1 mg l -1 Fe 2+ and 121.6 mg l -1 H 2O 2. Photo-Fenton degradation led to 76.7% mineralisation. Biodegradability during optimisation was evaluated by using the BOD 5/COD ratio; this value increased from 0.04 at the beginning of the process to 0.52 in t 30W = 20 min, thereby showing the effectiveness of using biological treatments.

Keywords


Pesticide; carbofuran; photo-Fenton; biodegradability; Box-Benkhen design

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ISSN: 0120-5609 (print)
ISSN: 2248-8723 (online)

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Publindex is a Colombian bibliographic index for classifying, updating, rating and certifying scientific and technological publications. It is recognised by COLCIENCIAS and ICFES in Colombia.

Directory of Open Access Journals

DOAJ increases the visibility and ease of use of open access scientific and scholarly journals, aims to be comprehensive and cover all that journals that use a quality control system to guarantee the content. It's a one stop shop for users of OA Journals.

SciELO Colombia

SciELO Colombia is a virtual library for Latin-America, the Caribbean, Spain and Portugal, which was created by FAPESP in 1997 in Sao Pablo, Brazil. It is currently being managed in Colombia by the Universidad Nacional de Colombia.

e-Revistas

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Redalyc

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Dialnet

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Universidad Nacional de Colombia
Carrera 45 No 26-85 - Edificio Uriel Gutiérrez
Bogotá D.C. - Colombia