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Hexakis(acetonitrile-N)ruthenium(II) bis(hexabromocarbadodecaborate) acetonitrile solvate

Acta Crystallographica Section E

Structure Reports Online

Volume 66, Part 3 (March 2010)


metal-organic compounds



ez2197 scheme

Acta Cryst. (2010). E66, m325-m326    [ doi:10.1107/S1600536810006252 ]

Hexakis(acetonitrile-[kappa]N)ruthenium(II) bis(hexabromocarbadodecaborate) acetonitrile solvate

J. Masland, J. Diaz, S. Eady, E. Lobkovsky and A. Larsen

Abstract: The title compound, [Ru(NCCH3)6](CH6B11Br6)2·CH3CN, consists of the 'naked' ruthenium(II) cation surrounded by six acetonitrile molecules, each coordinated via the nitrogen atoms in a linear or nearly-linear fashion in a typical octahedral over-all arrangement. The cation is balanced by the two hexa-bromocarborane cage anionic fragments [CB11H6Br6]. Weak C-H...Br and B-H...Br interactions link neighboring anions.

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