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Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-2N,N'}neodymium(III)

Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 5 (May 2012)


metal-organic compounds



zs2190 scheme

Acta Cryst. (2012). E68, m578-m579    [ doi:10.1107/S1600536812014055 ]

Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-[kappa]2N,N'}neodymium(III)

H. Yang

Abstract: In the title compound, [NdCl3(C12H10N2O)3], the central NdIII ion is nine-coordinated by six N atoms from three bidentate chelate N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine ligands and three Cl- ions, and displays a distorted tricapped trigonal prismatic geometry. The complex molecules are stabilized by intramolecular O-H...Cl hydrogen bonds.

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