Acta Crystallographica Section E

Structure Reports Online

Volume 66, Part 12 (December 2010)

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organic compounds

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2-(Methylsulfinyl)benzamide

Z. Yan

Abstract: In the crystal of the title compound, C₈H₉NO₂S, synthesized by the oxidation of 2-(methylsulfanyl)benzamide using NaOCl with 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) as the catalyst, molecules are linked via intermolecular N-HO_amide hydrogen bonds, forming centrosymmetric amide-amide dimers which are extended into a two-dimensional lamellar framework parallel to (100) through amide-sulfinyl N-HO hydrogen bonds. The benzene ring forms a dihedral angle of 25.6 (2)° with the amide group

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