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Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 9 (September 2012)


metal-organic compounds



bt5972 scheme

Acta Cryst. (2012). E68, m1217    [ doi:10.1107/S1600536812036161 ]

Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-[kappa]2S,S']lead(II)

E. Sathiyaraj, S. Thirumaran and S. Selvanayagam

Abstract: The molecule of the title compound, [Pb(C16H16NS2)2], is located on a twofold rotation axis, which runs through the PbII atom. The two dithiocarbamate ligands coordinate the metal in a pyramidal configuration through the S atoms. The two phenyl rings of each dithocarbamate ligand are aligned at a dihedral angle of 78.4 (1)°. The molecular conformation is stabilized by intramolecular C-H...S interactions.

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