It is the cache of ${baseHref}. It is a snapshot of the page. The current page could have changed in the meantime.
Tip: To quickly find your search term on this page, press Ctrl+F or ⌘-F (Mac) and use the find bar.

[Bis(pyridin-2-ylmethyl)amine-3N,N',N'']tricarbonylrhenium(I) bromide hemihydrate

Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 6 (June 2012)


metal-organic compounds



ru2033 scheme

Acta Cryst. (2012). E68, m741-m742    [ doi:10.1107/S1600536812019654 ]

[Bis(pyridin-2-ylmethyl)amine-[kappa]3N,N',N'']tricarbonylrhenium(I) bromide hemihydrate

M. Schutte, T. J. Muller, H. G. Visser and A. Roodt

Abstract: The title compound, fac-[Re(C12H12N3)(CO)3]Br·0.5H2O, crystallizes with a cationic rhenium(I) unit, a bromide ion and half a water molecule, situated on a twofold rotation axis, in the asymmetric unit. The ReI atom is facially surrounded by three carbonyl ligands and a tridentate bis(pyridin-2-ylmethyl)amine ligand in a distorted octahedral environment. N-H...Br, O-H...Br, C-H...O and C-H...Br hydrogen bonds are present in the crystal structure and [pi]-[pi] stacking is also observed [centroid-centroid distances = 3.669 (1) Å and 4.054 (1) Å], giving rise to a three-dimentional network. The molecules pack in a head-to-head fashion along the ac plane.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster