It is the cache of ${baseHref}. It is a snapshot of the page. The current page could have changed in the meantime.
Tip: To quickly find your search term on this page, press Ctrl+F or ⌘-F (Mac) and use the find bar.

Bis(benzoato-2O,O')(1,10-phenanthroline-2N,N')lead(II) benzoic acid monosolvate

Acta Crystallographica Section E

Structure Reports Online

Volume 66, Part 12 (December 2010)


metal-organic compounds



bt5413 scheme

Acta Cryst. (2010). E66, m1661-m1662    [ doi:10.1107/S1600536810048725 ]

Bis(benzoato-[kappa]2O,O')(1,10-phenanthroline-[kappa]2N,N')lead(II) benzoic acid monosolvate

J. Dai, J. Yang and J. Li

Abstract: The reaction of lead acetate, benzoic acid and 1,10-phenanthroline (phen) in aqueous solution yielded the title complex, [Pb(C7H5O2)2(C12H8N2)]·C7H6O2. In the crystal, the PbII ion is hexacoordinated by two N atoms from one 1,10-phenanthroline ligand and four O atoms from two chelate benzoate anions. If the second benzoate ligand is treated as one coordination site, the overall coordination may be represented as a distorted pseudo-square pyramid. An intermolecular O-H...O hydrogen bond links the solvent benzoic acid molecule with a metal-coordinated benzoate ligand. The shortest Pb...Pb distance is 3.864 (4) Å, indicating a weak metal-metal interaction. Two complex molecules related by an inversion centre form dimeric units via Pb...O interactions of 3.206 (4) Å.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster